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Simplified etymology
Archbishop is recorded in Old English. Its prefix arch-, meaning “chief” or “principal,” comes ultimately from Greek arkhos, “chief” or “ruler,” and marks the bishop as one of superior rank.
Etymology
From Middle English archebischop and Old English arcebiscop, ultimately from Ecclesiastical Latin archiepiscopus and Greek arkhiepiskopos. It combines arkhi-, 'chief or first,' with episkopos, 'overseer,' the source of bishop. The compound therefore literally denotes a chief bishop.