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Simplified etymology
Pontiff entered English in the late 16th century through French pontife from Latin pontifex, literally “bridge-maker.” In ancient Rome, pontifex was the title of a member of the principal college of priests; in English, pontiff came to refer especially to the pope.
Etymology
From Middle English pontif, through Old French, from Latin pontifex, the title of a member of Rome's principal college of priests. Christians later applied the title to bishops and especially to the bishop of Rome, producing the modern formal synonym for pope.