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Simplified etymology
Alms comes from Old English ælmesse, borrowed through Christian Latin eleemosyna from Greek eleēmosunē “compassion,” based on eleos “mercy.” Its final s was part of the original word rather than a plural ending, and the singular phrase “an alms” remained in use until the mid-16th century.
Etymology
From Old English aelmesse, through Late Latin eleemosyna from Ancient Greek eleemosyne, 'pity, mercy, charity,' based on eleemon, 'merciful.' Despite its final s, alms functions in modern English as a mass noun or a plural-form noun.