The Outline of Science, Volume 1

We have already learnt something of the principles of the spectroscope, the instrument which, by making it possible to learn the actual constitution of the stars, has added a vast new domain to astronomy. In the simplest form of this instrument the analysing portion consists of a single prism. Unless the prism is very large, however, only a small degree of dispersion is obtained. It is obviously desirable, for accurate analytical work, that the dispersion—that is, the separation of the different parts of the spectrum—should be as great as possible. The dispersion can be increased by using a large number of prisms, the light emerging from the first prism, entering the second, and so on. In this way each prism produces its own dispersive effect and, when a number of prisms are employed, the final dispersion is considerable. A considerable amount of light is absorbed in this way, however, so that unless our primary source of light is very strong, the final spectrum will be very feeble and hard to decipher. Another way of obtaining considerable dispersion is by using a diffraction grating instead of a prism. This consists essentially of a piece of glass on which lines are ruled by a diamond point. When the lines are sufficiently close together they split up light falling on them into its constituents and produce a spectrum.[Pg 51] The modern diffraction grating is a truly wonderful piece of work. It contains several thousands of lines to the inch, and these lines have to be spaced with the greatest accuracy. But in this instrument, again, there is a considerable loss of light. We have said that every substance has its own distinctive spectrum, and it might be thought that, when a list of the spectra of different substances has been prepared, spectrum analysis would become perfectly straightforward. In practice, however, things are not quite so simple. The spectrum emitted by a substance is influenced by a variety of conditions. The pressure, the temperature, the state of motion of the object we are observing, all make a difference, and one of the most laborious tasks of the modern spectroscopist is to disentangle these effects from one another. Simple as it is in its broad outlines, spectroscopy is, in reality, one of the most intricate branches of modern science.