Discoveries and Inventions of the Nineteenth Century

wire is formed by a method identical with that used in the fabrication of the leaden rope for making bullets (p. 330); that is to say, the metal is forced in a heated and softened state through a small opening in an iron cylinder. The intensity of the magnesium light has been measured by Bunsen and Roscoe. They say that 72 grains of magnesium, when properly burnt, evolve as much light as 74 stearine candles burning for ten hours, and consuming 20 lbs. of stearine. Lamps in which magnesium may be steadily burnt are made by Mr. F. W. Hart, of London. In the more elaborate forms of these lamps, there are springs and wheels for pushing forward the magnesium ribbon, or a strand of magnesium wire, into the flame of a spirit-lamp; while at the same time the magnesium wire is made to revolve on its axis, in order to overcome its tendency to bend down, which would be a great disadvantage when the light is used for optical apparatus. But for ordinary purposes a much simpler arrangement suffices: the magnesium ribbon or wire is coiled on a drum, from which it is drawn off by passing between two little rollers, which are turned by hand. The wire or ribbon is drawn off the drum by the rollers, and pushed forward through a guiding tube, which brings it into the apex of the flame of a spirit-lamp. In this simpler form of lamp the rate is, of course, directly dependent on the person who turns the winch of the feeding-rollers; but in the automatic lamp there are appliances for adjusting the rate; the suitable speed must be first found by trial, and then the apparatus is to be regulated accordingly. By means of these lamps photographs can be taken as quickly as with sunlight, on account of the abundance of chemically-active rays given out by the burning magnesium. It has been found that an equivalent of magnesium, in combining with oxygen, liberates a larger amount of heat than the equivalent quantity of any other metal, not excluding even potassium. Magnesium forms alloys with several other metals, such as lead, tin, mercury, gold, silver, platinum. All these alloys are brittle, and have a granular or crystalline fracture. They are too readily acted on by air and moisture to be of any service in the arts. The alloy of 85 parts of tin with 15 of magnesium is hard and brittle; its colour is lavender, although both constituents are white, or nearly so; and it decomposes water at ordinary temperatures. Both metallic magnesium and aluminium furnish useful re-agents to the scientific chemist. The latter metal, when fused, dissolves boron, silicon, and titanium, and on cooling deposits these elements in the crystalline form, this being the only known process for artificially preparing them in the crystalline state. Since the above paragraphs were written, the price of sodium has been further greatly reduced, and it can now (1890) be purchased in bulk at about 4s. per lb. This cheapness has brought the substance into use for the reduction of other metals and one consequence has been a great fall in 722the price of aluminium. At Salindres, in France, the process of obtaining this metal that has been described on page 587, has been in use for many years, during which considerable quantities of aluminium have been produced, the output for 1882 being stated as 5,280 lbs. Aluminium has lately been prepared by a company at Wallsend-on-Tyne from cryolite, a mineral which is found only in Greenland, but occurs there in great abundance. Cryolite is a double fluoride of aluminium and sodium, and the processes for its reduction consist in fusing it with common salt in a reverberatory furnace, drawing off the mixture into an iron vessel, and stirring into the fused mass a certain quantity of sodium. This produces a violent action, on the cessation of which the slag is poured off, and the metallic aluminium is found as a “button” at the bottom of the converter. For obtaining a purer metal, the fusion is made in crucibles, and the sodium is added in two operations without removing the crucible. The yield of aluminium is about 8 per cent. of the weight of cryolite, and three parts of sodium are required to furnish one part of aluminium. Another large manufactory of aluminium is in operation at Oldbury, near Birmingham. There is a special difficulty in the metallurgy of aluminium, arising from the fact of the qualities of the metal being much deteriorated by the presence of a very small amount of foreign matters such as iron, silicon, &c., at the same time that no process has been found for purifying the product from these substances. If the aluminium is to be pure it must be so prepared at the first. Electrolysis has been proposed as a means of reducing the compounds, and obtaining the metal free from admixtures. Experiments seem to show that the dynamo-electric machine may be applied to this purpose, as well as to the reduction of sodium compounds, when certain practical difficulties arising from the chemical energies of the liberated substances have been overcome. What is called the “electric” furnace has been successfully used in the production of aluminium bronze. It is a rectangular iron box, 5 feet long, 1 foot deep, and 15 inches wide, with electrodes formed of rods of carbon 30 inches long and 3 inches in diameter. It is charged with a mixture of 25 parts of corundum (native crystallized oxide of aluminium), 12 parts of carbon, and 50 parts of granulated copper. This is covered at the top by lumps of charcoal, and a lid is fastened over the whole. The current from a powerful dynamo is sent through the carbons, and in about ten minutes the copper is melted, when the electrodes, at first only a few inches apart, are moved to an increased distance, and the strength of current increased. The corundum is reduced, the aluminium alloying itself with copper, and the oxygen combining with the carbon to form carbon monoxide, which is driven off. The resulting alloy is cast into ingots, its percentage of aluminium ascertained, and then it is melted with enough copper to produce aluminium bronze (page 719). The price of aluminium, which was as already stated about 3s. per ounce in 1875, has been so much reduced that the metal may now (1890) be purchased for 11s. or 12s. per lb. We may therefore expect to see wider applications of its excellent qualities. Though the price per lb. is still much higher than that of copper-–22 or more times as much—the metal is so much lighter that a lb. of aluminium occupies nearly 3⅓ times the space of a lb. of copper, so that, taking bulk for bulk, aluminium is only about seven times as dear as copper. [1890.] When first introduced by Deville, in 1854, aluminium cost £20 per lb.; but its prospective value for application in the arts was recognised, and in two or three years afterwards it was put on the market at 40s. per lb. 723It was then, as already remarked, applied to many purposes where lightness is desirable, such as for the tubes of telescopes, opera-glasses, the mounting of photographic lenses, &c. And in 1888, when the production of sodium had been cheapened and applied to the separation of aluminium, the price of the latter metal fell to 18s. per lb. In the meantime, the cheap electricity of the dynamo caused attention to be again directed to the original electrolytic method; but many difficulties in detail had to be overcome in applying this process on the commercial scale. At length the sodium process was superseded; and by the beginning of 1890, a Swiss company was producing aluminium at 11s. per lb. In the course of the following year they succeeded in bringing the price down to 2s. per lb.; and again three years later, namely at the beginning of 1894, they could offer the metal at 1s. 7d. per lb. The conditions required for effecting this great reduction were found in driving the dynamo machinery by water-power, and in an abundant supply of cryolite at moderate cost. This cheapness of production at once placed the Swiss company in the position of being the largest and most successful aluminium manufacturers in the world, so that in 1892 they had realised a net profit of £21,563, paying their shareholders 8 per cent., and, further, in 1893, the net profit was half as much again, and the dividend was increased to 10 per cent. A British aluminium company has recently been formed in London for acquiring the rights of working all the processes of the successful Swiss company, purchasing outstanding English patents, amalgamating with certain existing companies, and for working the bauxite deposits in Ireland, &c., &c. There is every reason to believe that an important result of this enterprise will be a still further reduction in the price of this metal, and consequently a great extension of its applications. And now (September, 1895) we have already heard of a further reduction in the price of this metal, which, at the present time, can be purchased in bulk for about 1s. 6d. per lb. 724 Fig. 337.—Portrait of Mr. Thomas Hancock.