Discoveries and Inventions of the Nineteenth Century

crystal, according as the crystal is presented to it in different directions round the ray as an axis. The ray of light is no longer uniform in its properties all round, but appears to have acquired different sides, as it were, in passing through the rhomb of Iceland spar. This condition is indicated by saying that the ray is polarized, and the first rhomb of spar is termed the polarizer, while the second rhomb, by which we recognize the fact that both the ordinary and the extraordinary rays emerge having different sides, has received the name of analyser. But, in order to study conveniently all the phenomena in Iceland spar, we should have crystals of a considerable size, otherwise the two rays do not become sufficiently separated so as to make it an easy matter to intercept one of them while we examine the other. A very ingenious mode of getting rid of one of the rays was devised by Nicol, and as his apparatus is much used for experiments on polarized light, we shall state the mode of constructing Nicol’s Prism. It is made from a rhomb of Iceland spar, Fig. 207, in which a and b are the corners where the three obtuse angles meet, all equal. If we draw through a and b lines bisecting the angles d a c and f h g, and join a b, these lines will all be in one plane, which is a principal section of the crystal, and contains the axis, a b. Now suppose another plane, passing through a b, to be turned so that it is at right angles to the plane containing a b and the bisectors: this plane would cut the sides of the crystal in the lines a i, i h, b k, k a; and in making the Nicol prism, the crystal is cut into two along 404this plane, and the two pieces are then cemented together by Canada balsam. A ray of light, R, entering the prism, undergoes double refraction; but the ordinary ray, meeting the surface of the Canada balsam at a certain angle greater than the limiting angle, is totally reflected, and passes out of the crystal at O; while the extraordinary ray, meeting the layer of balsam at a less angle than its limiting angle, does not undergo total reflection, but passes through the balsam, and emerges in the direction of E, completely polarized, so that the ray is unable to penetrate another Nicol’s prism of which the principal section is placed at right angles to that of the first. Fig. 208. Among other crystals which possess the property of doubly refracting, and therefore of polarizing, is the mineral called tourmaline, which is a semi-transparent substance, different specimens having different tints. In Fig. 208, A, B, represent the prismatic crystals of tourmaline, and C shows a crystal which has been cut, by means of a lapidary’s wheel, into four pieces, the planes of division being parallel to the axis of the prism. The two inner portions form slices, having a uniform thickness of about 120 in., and when the faces of these have been polished, the plates form a convenient polarizer and analyser. Let us imagine one of the plates placed perpendicularly between the eye and a lighted candle. The light will be seen distinctly through it, partaking, however, of the colour of the tourmaline; and if the plate be turned round so that the direction of the axis of the crystal takes all possible positions with regard to the horizon, while the plane of the plate is always perpendicular to the line between the eye and the candle, no change whatever will be seen in the appearance of the flame. But if we fix the plate of crystal in a given position, let us say with the axial direction vertical, and place between it and the eye the second plate of tourmaline, the appearances become very curious indeed, and the candle is visible or invisible according to the position of this second plate. When the axis of the second is, like that of the first, vertical, the candle is distinctly seen; but when the axis of the second plate is horizontal, no rays from the candle can reach the eye. If the second plate be slowly turned in its own plane, the candle becomes visible or invisible at each quarter of a revolution, the image passing through all degrees of brightness. Thus the luminous rays which pass through the first plate are polarized like those which emerge from a crystal of Iceland spar. It is not necessary that the plates used should be cut from the same crystal of tourmaline, for any two plates will answer equally well which have been cut parallel to the axes of the crystals which furnished them. In the case of tourmaline the extraordinary ray possesses the power of penetrating the 405substance of the crystal much more freely than the ordinary ray, which a small thickness suffices to absorb altogether. It may be noted that in the simple experiment we have just described, the plate of tourmaline next the candle forms the polarizer, and that next the eye the analyser; and that until the latter was employed, the eye was quite incapable of detecting the change which the light had undergone in passing through the first plate, for the unassisted eye had no means of recognizing that the rays emerged with sides. The usual manner of examining light, to find whether it is polarized, is to look through a plate of tourmaline or a Nicol’s prism, and observe whether any change in brightness takes place as the prism or plate is rotated. Now, it so happened that in 1808 a very eminent French man of science, named Malus, was looking through a crystal of Iceland spar, and seeing in the glass panes of the windows of the Luxembourg Palace, which was opposite his house, the image of the setting sun, he turned the crystal towards the windows, and instead of the two bright images he expected to see, he perceived only one; and on turning the crystal a quarter of a revolution, this one vanished as the other image appeared. It was, indeed, by a careful analysis of this phenomenon that Malus founded a new branch of science, namely, that which treats of polarized light; and his views soon led to other discoveries, which, with their theoretical investigations, constitute one of the most interesting departments of optical science, as remarkable for the grasp it gives of the theory of light as for the number of practical applications to which it has led. The accidental observation of Malus led to the discovery that when a ray of ordinary light falls obliquely on a mirror—not of metal, but of any other polished surface, such as glass, wood, ivory, marble, or leather—it acquires by reflection at the surface the same properties that it would acquire by passing through a Nicol’s prism or a plate of tourmaline: in a word, it is polarized. Thus, if a ray of light is allowed to fall upon a mirror of black glass at an angle of incidence of 54° 35´, the reflected ray will be found to be polarized in the plane of reflection—that is, it will pass freely through a Nicol’s prism when the principal section is parallel to the plane of reflection; but when it is at right angles to the latter, the reflected ray will be completely extinguished by the prism—that is, it is completely polarized. If the angle of the incident ray is different from 54° 35´, then the reflected ray is not completely intercepted by the prism—it is not completely but only partially polarized. The angle at which maximum polarization takes place varies with the reflecting substance; thus, for water it is 53°, for diamond 68°, for air 45°. A simple law was discovered by Sir David Brewster by which the polarizing angle of every substance is connected with its refractive index, so that when one is known, the other may be deduced. It may be expressed by saying that the polarizing angle is that angle of incidence which makes the reflected and the refracted rays perpendicular to each other. The refracted rays are also found to be polarized in a plane perpendicular to that of reflection. Fig. 209.—Polariscope. Fig. 210. Fig. 211.—Iceland Spar showing Double Refraction. Instruments of various forms have been devised for examining the phenomena of polarized light. They all consist essentially of a polarizer and an analyser, which may be two mirrors of black glass placed at the polarizing angle, or two bundles of thin glass plates, or two Nicol’s prisms, or two plates of tourmaline, or any pair formed by two of these. Fig. 209 represents a polariscope, this instrument being designed to permit any desired combination of polarizer and analyser, and having graduations for measuring the angles, and a stage upon which may be placed various substances 406in order to observe the effects of polarized light when transmitted through them. It is found that thin slices of crystals placed between the polarizer and analyser exhibit varied and beautiful effects of colour, and by such effects the doubly refracting power of substances can be recognized, where the observation of the production of double images would, on account of their small separation, be impossible. And the polariscope is of great service 407in revealing structures in bodies which with ordinary light appear entirely devoid of it—such, for example, as quill, horn, whalebone, &c. Except liquids, well-annealed glass, and gelatinous substances, there are, in fact, few bodies in which polarized light does not show us the existence of some kind of structure. A very interesting experiment can be made by placing in the apparatus, shown in Fig. 210, a square bar of well-annealed glass; on examining it by polarized light, it will be found that before any pressure from the screw C is applied to the glass, it allows the light to pass equally through every part of it; but when by turning the screw the particles have been thrown into a state of strain, as shown in the figure, distinct bands will make their appearance, arranged somewhat in the manner represented; but the shapes of the figures thus produced vary with every change in the strain and in the mode of applying the pressure. 408 Fig. 212.