The Story of Electricity

ELECTRO-CHEMISTRY AND ELECTRO-METALLURGY. In no department of the application of electricity to practical work has there been a greater development than in electro- metallurgy and electro-chemistry. To-day there are vast industries depending upon electrical processes and the developments of a quarter of a century have been truly remarkable. Already more than one-half of the copper used in the arts is derived by electrolytic refining. The production of aluminum depends entirely on electricity, the electric furnace as a possible rival to the blast furnace for the production of iron and steel is being seriously considered, and many other metallurgical processes are being undertaken on a large scale. We have seen in our chapter on Electrolysis how a metal may be deposited from a solution of its salt and how this process could be used for deriving a pure metal or for plating or coating with the desired metal the surface of another metal or one covered with graphite. In the following pages it is intended to take up some of the more notable accomplishments in this field achieved by electricity, which have been developed to a state of commercial importance. The electric arc not only supplies light, but heat of great intensity which the electrical engineer as well as the pure scientist has found so valuable for many practical operations. It is of course obvious that for most chemical operations, and especially in the field of metallurgy, heat is required for the separation of combinations of various elements, for their purification, as well as for the combination with other elements into alloys or compounds of direct utility. The usual method of generating heat is by the combustion of some fuel, such as coal, coke, gas or oil, and this has been utilized for hundreds of years in smelting metals and ores and in refining the material from a crude state. Now it may happen that a nation or region may be rich in metalliferous ores, but possess few, if any, coal deposits. Accordingly the ore must be mined and transported considerable distances for treatment and the advantages of manufacturing industries are lost to the neighborhood of its original production. But if water power is available, as it is in many mountainous countries where various ores are found, then this power can be transformed into electricity which is available as power not only in various manufacturing operations, but for primary metallurgical work in smelting the ores and obtaining the metal therefrom. A striking instance of this is the kingdom of Sweden, which contains but little coal, yet is rich in minerals and in water power, so that its waterfalls have been picturesquely alluded to as the country's "white coal." Likewise, at Niagara Falls a portion of the vast water power developed there has been used in the manufacture of aluminum, calcium carbide, carborundum, and other materials, while at other points in the United States and Canada, not to mention Europe, large industries where electricity is used for metallurgical or chemical work are carried on and the erection of new plants is contemplated. The application of electricity to metallurgical and chemical work has been, in nearly all cases, the result of scientific research, and elaborate experimental laboratories are maintained by the various corporations interested in the present or future use of electrical processes. It is recognized by many of the older workers in this field that electrical developments are bound to come in the near future, and while they have not installed such appliances in their works yet they are keeping close watch of present developments, and in many cases experimental investigation and research is being carried on where electrical methods have not yet been introduced generally into the plant. Prior to 1886 the refining of copper was the only electro- metallurgical industry and at that time it was carried on on a very limited scale. To-day the production of electrolytic copper as an industry is second in importance only to the actual production of that metal. From the small refinery started by James Elkington at Pembury in South Wales, a vast industry has developed in which there has been a change in the size of operations and in the details of methods rather than in the fundamental process. For a solution of copper sulphate is employed as the electrolyte, blocks of raw copper as the anodes, and thin sheets of pure copper as the cathodes. The passage of the electric current, as we have seen on page 79, in the chapter on Electrolysis, is able to decompose the copper in the electrolyte and to precipitate chemically pure copper on the cathode, the copper of the solution being replenished from the raw material used as the anode by which the current is passed into the bath. At this Welsh factory 250 tons yearly were produced, and small earthenware pots sufficed for the electrolyte. Thirty years later one American factory alone was able to produce at least 350 tons of electrolytic copper in twenty-four hours, and over 400,000 tons is the aggregate output of the refineries of the world, which is about 53 per cent, of the total raw copper production. Of this amount 85 per cent, comes from American refineries, whose output has more than doubled since 1900. The chief reason for this increased output of electrolytic copper has been the great demand for its use in the electrical industries where not only a vast amount is consumed, but where copper of high purity, to give the maximum conductivity required by the electrical engineer, is demanded. When it is realized that every dynamo is wound with copper wire and that the same material is used for the trolley wire and for the distribution wires in electric lighting, it will be apparent how the demand for copper has increased in the last quarter of a century. Electrolytic methods not only supply a purer article and are economical to operate, especially if there is water power in the vicinity, but the copper ores contain varying amounts of silver and gold which can be recovered from the slimes obtained in the electrolytic process. Wherever possible machinery has been substituted for hand labor, the raw copper anodes have been cast, and the charging and discharging of the vats is carried on by the most modern mechanical methods in which efficiency and economy are secured. On the chemical side of the process attempts have been made to improve the electrolyte, notably by the addition of a small amount of hydrochloric acid to prevent the loss of silver in the slimes, and this part of the work is watched with quite as much care as the other stages. Electric furnaces have also been constructed for smelting copper ores, but these have not found wide application, and the problem is one of the future. For the most part the copper electrically refined is produced in an ordinary smelter. The mints of the United States are now all equipped with electrolytic refining plants to produce the pure metal needed for coinage and they have proved most satisfactory and economical. As the electrolytic production of copper is an industry of great present importance, so the production of iron and steel by electricity promises to be of the greatest future importance. Electric furnaces for making steel are now maintained, and the industry has passed beyond an experimental condition. But it has not reached the point where it is competing with the Bessemer or the open hearth process of the manufacture of steel, while for the smelting of iron ores the electric furnace has not yet been found practical from an economic standpoint. Before 1880 Sir William Siemens showed that an electric arc could be used to melt iron or steel in a crucible, and he patented an electric crucible furnace which was the first attempt to use electricity in iron and steel manufacture. He stated that the process would not be too costly and that it had a great future before it. This was an application of the intense heat of the arc, which supplies a higher temperature than any source known except that of the sun. This heat is used to melt the metal, in which condition various impurities can be removed and necessary ingredients added. Siemens' furnace did not find extensive application, largely on account of the great metallurgical developments then taking place in the iron industry and the thorough knowledge of metallurgical processes as carried on, possessed by metallurgical engineers. But the idea by no means languished, and in 1899 Paul Heroult and other electro-metallurgists were active in developing a practical electric furnace for iron and steel work. The Swedish engineer, F. A. Kjellin, was also active and as the result of the efforts of these and other workers, by 1909 electric furnaces were employed, not only in the manufacture of special steels whose composition and making were attended with special care, but for rails and structural material. There were reported to be between thirty and forty electric steel plants in various countries, and the outlook for the future was distinctly bright. The application of electro- metallurgy at this time was confined to the manufacture of steel, as the smelting of iron had not emerged from the experimental stage of its development, though extensive trials on a large scale of various furnaces have been undertaken in Europe and by the Canadian government at Sault Ste. Marie, where the Heroult furnace, soon to be described, was employed. Electro-metallurgy of steel, as in all utilization of electrical power, depends upon obtaining electricity at a reasonable cost, and then utilizing the heat of the arc or of the current in the most practical and economical form. One of the pioneer furnaces for this purpose which has seen considerable development and practical application is the Heroult furnace, which is a tilting furnace of the crucible type, whose operation depends upon both the heat of the arc and on the heat produced by the resistance of the molten material. In the Heroult process the impurities of the molten iron are washed out by treatment with suitable slags. The furnace consists of a crucible in the form of a closed shallow iron tank, thickly lined with dolomite and magnazite brick, with a hearth of crushed dolomite. The electric current enters the crucible through two massive electrodes of solid carbon, 70 inches in length and 14 inches in diameter, so mounted that they can be moved either vertically or horizontally by the electrician in charge. These electrodes are water-jacketed to reduce the rate of consumption. The furnace contains an inlet for an air blast and openings in its covering for charging the material and for the escape of the gases. The actual process of steel-making consists of charging the crucible with steel scrap, pig iron, iron ore, and lime of the proper quality and in the right proportions, placing this material on the hearth of the furnace. Combined arc and resistance heating is applied to raise the charge to the melting point. The current is of 120 volts or the same as that used in an ordinary incandescent lighting circuit, but is alternating and of 4,000 amperes. This is for a three-ton furnace. As the material melts the lime and silicates form a slag which fuses rapidly and covers the iron and steel in the crucible, so that the molten bath is protected from the action of the gases which are liberated and the oxygen in the atmosphere. The next step in the process is to lower the electrodes until they just touch beneath the surface of the molten slag so that subsequent heating is due not to the effect of the arc but to the resistance which the bath offers to the passage of the current. Air from an air blast is introduced into the crucible to oxidize the impurities of the metal, particularly the sulphur and the phosphorus which are carried into the slag and this is removed by the tilting of the furnace. Fresh quantities of lime, etc., are added, and the operation is repeated until a comparatively pure