Discoveries and Inventions of the Nineteenth Century

to traverse the whole length of the spectrum. It might at first sight appear as if any ordinary spider’s web or parallel wire micrometer might be used instead of this contrivance. But on closer attention it will be seen that as the spectrum will not permit of magnification by the use of lenses, the line of such an ordinary micrometer could not be brought to focus and rendered visible. The bright pointer of the new arrangement possesses this great advantage—that it does not illuminate the whole field of view. If a dark wire were used, the bright diffused light would almost obscure the faint light of the spectra, and entirely prevent the possibility of seeing, let alone measuring, the position of lines or bands in the most refrangible part of the spectrum. To produce good effects with this apparatus the upper surface of the compound prism, P, must make an angle of exactly 45° with the sides of 435the tube. Under these circumstances the limits of correction for the path of the rays in their passage through the dispersing prisms are very limited and must be strictly observed. The usual method of correcting by the outer surface is inadmissible. For the sake of simplicity, some of the work of the lower part of the micro-spectroscope is omitted in the engraving. As to the method of using this contrivance: With the apparatus just described, measure the position of the principal Fraunhofer’s lines in the solar spectrum. Let this be done carefully, in bright daylight. A little time given to this measurement will not be thrown away, as it will not require to be done again. Note down the numbers corresponding to the position of the lines, and draw a spectrum from a scale of equal parts. About 3 in. will be found long enough for this spectrum; but it may be made as much longer as is thought desirable, as the measurements will not depend in any way on the distance of these lines apart, but only on the micrometric numbers attached to them. Let this scale be done on cardboard and preserved for reference. Now measure the position of the dark bands in any absorption spectra, taking care for this purpose to use lamplight, as daylight will give, of course, the Fraunhofer lines, which will tend to confuse your spectrum. If the few lines occurring in most absorption spectra be now drawn to the same scale as the solar spectrum, on placing the scales side by side, a glance will show the exact position of the bands in the spectrum relatively to the Fraunhofer lines, which thus treated form a natural and unchangeable scale (see diagram, Fig. 226). But for purposes of comparison it will be found sufficient to compare the two lists of numbers representing the micrometric measures, simply exchanging copies of the scale of Fraunhofer lines, or the numbers representing them will enable observers at a distance from each other to compare their results, or even to work simultaneously on the same subject. Fig. 226. A simpler form of the micro-spectroscope is also made by Mr. Browning at a very modest price, and if the reader possesses a microscope, and desires to examine these interesting subjects for himself, he will do well to procure this instrument, instead of that represented in Fig. 220, as it will also answer better for other purposes. A section of the instrument is shown in Fig. 227. When used with the microscope it is slipped into the place of the eye-piece. There is an adjustable slit, a reflecting prism, by which two different spectra may be examined at once, and a train of five prisms for dispersing the rays. It can be used equally well for seeing the bright lines 436of metals and the Fraunhofer lines, and for viewing any two spectra simultaneously. These direct-vision spectroscopes are better adapted for general use by those who have not several different instruments, than such forms as that shown in Fig. 229, for in the direct-vision instruments the whole extent of the spectrum is visible at one view, which is by no means the case with the larger instruments. Fig. 227.—Section of Micro-Spectroscope. CELESTIAL CHEMISTRY AND PHYSICS. We now approach that portion of our subject in which its interest culminates, for however remarkable may be some of the above-named results of this searching optical analysis, they are surpassed by those which have been obtained in the field upon which we are about to enter. The cause of the dark lines which Fraunhofer observed in the light of the sun and of certain stars remained unexplained, he only establishing the fact that they must be due to some absorptive power existing in the sun and stars themselves, and not to anything in our atmosphere. It was reserved for Professor Kirchhoff, of the University of Heidelberg, to show the full significance of the dark lines. Fraunhofer had, on his first observation of the lines, noticed that the D lines were coincident with the bright lines in the spectrum of sodium. This interesting fact may be readily observed with any spectroscope which permits of the two spectra being simultaneously viewed. The bright line (or lines if the spectroscope be powerful) of the metal is seen as a prolongation of the dark D solar line. Even with an instrument like that shown in Fig. 220 the coincidence may be noticed. Let the observer receive into the instrument the rays in diffused daylight only, when he will still see the principal Fraunhofer lines distinctly, and let him note the exact position of the D line, while he brings in front of the slit the flame of a spirit-lamp charged with a little salt. He will then see the bright yellow line replacing the dark D line, and by alternately removing and putting back the lamp he will be soon convinced of the perfectly identical position of the lines. This fact remained without explanation from 1814 to 1859, when Kirchhoff accidentally found, to his surprise, that the dark D line could be produced 437artificially. He says: “In order to test in the most direct manner possible the frequently asserted fact of the coincidence of the sodium lines with the D lines, I obtained a tolerably bright solar spectrum, and brought a flame coloured by sodium vapour in front of the slit. I then saw the dark lines D, change into bright ones. The flame of a Bunsen’s lamp threw the bright sodium lines upon the solar spectrum with unexpected brilliancy. In order to find out the extent to which the intensity of the solar spectrum could be increased without impairing the distinctness of the sodium lines, I allowed the full sunlight to shine through the sodium flame, and, to my astonishment, I saw that the dark lines, D, appeared with an extraordinary degree of clearness. I then exchanged the sunlight for the Drummond’s or oxy-hydrogen lime-light, which, like that of all incandescent solid or liquid bodies, gives a spectrum containing no dark lines. When this light was allowed to fall through a suitable flame, coloured by common salt, dark lines were seen in the spectrum in the position of the sodium lines. The same phenomenon was observed if, instead of the incandescent lime, a platinum wire was used, which, being heated in the flame, was brought to a temperature near its melting point, by passing an electric current through it. The phenomenon in question is easily explained, upon the supposition that the sodium flame absorbs rays of the same degree of refrangibility as those it emits, whilst it is perfectly transparent for all other rays.” (Quoted in Roscoe’s Lectures on “Spectrum Analysis.”) When the light of ignited lime was similarly made to pass through flames containing the incandescent vapours of potassium, barium, strontium, &c., the bright lines which these substances would have produced had the lime-light not been present were found to be in every case changed into dark lines, occupying the very same positions in the spectrum. In such experiments the flames containing the metals in the vapourized state do all the time really give off those rays which are peculiar to each substance; but when a more intense illumination—such as the lime-light, the electric arc, or direct sunlight—passes through them, the rays of the spectrum produced by the intense light overpower those given off by the relatively feebly coloured flames, and hence the portions of the spectrum which are occupied by these, appear black. But as the intense light would give a perfectly continuous spectrum if the incandescent metallic vapour allowed the rays corresponding to its lines to pass through it, the inference is obvious that each vapour absorbs those particular rays which it has itself the power of emitting, but allows all others to pass freely through it. Besides the experimental proofs of this fact which have been already adduced, many others might be named. The flame of a spirit-lamp with a salted wick appears opaque and smoky when we look through it at a large flame of burning hydrogen, also coloured by sodium; for the rays emitted by the latter do not penetrate the former, which, in consequence of its feebler light, appears dark by comparison. Again, if an exhausted tube containing metallic sodium be heated so as to convert the sodium into vapour, the tube viewed by the light of a sodium flame appear to contain a black smoke, and the light from the flame will no more pass through it than through a solid object; yet the tube appears perfectly transparent when viewed by ordinary light, and the light from a lithium or other coloured flame would also pass freely. Kirchhoff was led by purely theoretical reasoning to conclude that all luminous bodies have precisely the same power of absorbing certain rays of light as they have of emitting them at the same temperature, and he thus brought luminous rays under the same general law which had 438previously been established for radiant heat by Prevost, Dessains, Balfour Stewart, and others. Here, then, a law was arrived at, and, abundantly confirmed by direct experiment as regards the more volatile metals, it was ready to supply the most satisfactory explanation of the coincidences which were everywhere discovered to exist between the Fraunhofer lines and those which belong to terrestrial substances. For Kirchhoff also found, when mapping the very numerous lines seen in the spark spectrum of iron, that for each of the 90 bright lines of iron which he then observed, there was a dark line in the solar spectrum exactly corresponding in position. The number of observed bright lines in the iron spectrum has been since extended to 460, and yet each is found to have its exact counterpart in a solar dark line. So many coincidences as these made it certain that these dark lines and the bright lines of iron must have a common cause, for the chances against the supposition that the agreement was merely accidental are enormous. Kirchhoff actually calculated, by the theory of probabilities, the odds against the supposition. He found it represented by 1,000,000,000,000,000,000 to 1. The result arrived at in the case of sodium at once suggested the explanation that these lines were produced by an absorptive effect of the vapour of iron. Now, the existence of such a vapour in our atmosphere could not be admitted, while the temperature of the sun was known to be exceedingly high, far higher, indeed, than any temperature we can produce by electricity, or any other means. Hence, Kirchhoff concluded that his observations proved the presence of the vapour of iron in the sun’s atmosphere with as much certainty as if the iron had been actually submitted to chemical tests. By the same reasoning, Kirchhoff also demonstrated the existence in the solar atmosphere of calcium, chromium, magnesium, nickel, barium, copper, and zinc. To these, other observers have added strontium, cadmium, cobalt, manganese, lead, potassium, aluminium, titanium, uranium, and hydrogen. It has also been demonstrated that a considerable number of the Fraunhofer lines are due to absorption in our