Discoveries and Inventions of the Nineteenth Century

Yorkshire. This is a carbonate of a grey or bluish colour caused by the presence of a little iron silicate. It contains also a considerable amount of phosphorus. How simple is the operation of obtaining iron from the ore has already been stated—that it is necessary only to surround lumps of ore by fuel in a fire urged by a natural or artificial blast, and then to hammer the mass extracted from the furnace so as to weld together the scattered particles of the metal, and at the same time squeeze out the associated slag and cinders, in order to obtain a coherent malleable piece, which can be reheated in a smith’s fire, and forged into any required form. It is no wonder therefore that iron was so produced by the ancient Britons; at any rate Cæsar found them well provided with iron implements and weapons. No doubt the Romans brought their more advanced skill to the working of the metal; but in the matter of treating the original ore, the methods they pursued on an extensive scale in Britain were of the 40rude kind already described. Indeed in localities where the Romans were known to have carried on their operations, the remains of their workings are almost always found on high ground, so that it may be inferred that they relied upon the winds to fan their fires, and their operations were incomplete and wasteful. The most extensive of them appear to have been in Sussex and Monmouthshire, in which last county there are places where the ground is in large areas covered by their cinders and refuse, and in this about 30 or 40 per cent. of iron occurs, so that for some centuries this material was found capable of being profitably reworked as a source of the metal. Iron continued to be produced in England during the middle ages with charcoal for fuel, but its export was forbidden, and whatever steel was required had to be imported from abroad. Afterwards German artisans were brought over for making steel, and soon afterwards the importation of shears, knives, locks, and other articles was prohibited. The native production of iron continued, and this consumed the forests so rapidly for the supply of charcoal, that various Acts were passed to restrain the iron-makers, in order to preserve the timber. In spite of these, the arts of smelting and working iron advanced apace: bellows were used for the blast, and then the works were brought down into the valleys, where water power could be employed to work them. The scarcity of charcoal fuel caused many attempts to supply its place with pit coal, but these met with small success, partly on account of the coal containing so much sulphur, and partly from the difficulty of obtaining with it a sufficiently high temperature, especially as the blowing apparatus was as yet very imperfect. At length, in the first half of the seventeenth century, the problem was solved by Dud Dudley, whose process was kept secret, but is believed to have consisted in supplying coal at the top of a higher furnace, in such a manner that the coal was converted into coke by the heat of the escaping gases before it reached the reducing zone of the furnace. This innovation was violently opposed by the charcoal smelters, who persecuted the inventor in every way, until their resistance was successful. But before the middle of the next century coke was regularly used in iron smelting, the process having been made successful by Darby at Coalbrookdale, and then many new applications of cast iron came into vogue. Coke being a substance burning less freely than charcoal, bellows were found inadequate to give the necessary blast, and were displaced by blowing cylinders, actuated at first by water wheels, but this uncertain and comparatively feeble source of power was soon superseded by the steam engine, the “fire engine,” for which, as we have seen, Watt obtained his patent in 1769. The furnaces were not then all engaged in producing the fusible metal now called cast or pig iron as are the huge blast furnaces we see at the present time. Indeed it was much to the disgust of the old iron smelter that occasionally his product turned out to be of the fusible kind, unworkable by the hammer, which therefore he regarded as worthless. At what date cast iron was first used is uncertain; but probably it was not long before the fourteenth century. The furnaces in use up to that time were small square walled-in structures only 3 or 4 feet high, and their effect would not greatly exceed that of a smith’s forge: but as improved blowing apparatus gave more power, they soon became enlarged into oval or round brick towers from 10 to 15 feet high, and they, like the small furnaces, could be made to yield either smith iron or steel by modifying the charge and the manner of applying the blast; while furnaces of dimensions exceeding a certain limit could no longer be trusted 41to turn out malleable metal, but they produced instead the cruder substance we call white pig iron, and this requires much subsequent treatment before it is converted into malleable or “merchant iron.” Nevertheless the demand for cast iron as such, and more particularly the adoption of improved methods of deriving malleable iron from it, caused further increase in the size and numbers of blast furnaces, until in the early part of our century 30 feet was not an unusual height, the highest one in England in 1830 attaining 40 feet. The total make of pig iron in England was in that year nearly 700,000 tons, perhaps about fifty times as much as it was a century before, and thirty years later (1860) it had risen to nearly 4,000,000 tons. These figures show the extraordinary expansion of the British iron manufacture in the earlier part of the century; and the still more extensive applications of iron during the next twenty years had the effect of almost doubling the produce in 1880, and of 42increasing also three-fold the amount of foreign metal imported, raising it to 2,500,000 tons. The reader will now, it is hoped, be prepared to follow with some interest a brief account of the principal inventions which have brought about results of such importance. Fig. 17.—Blast Furnace (Obsolete Type). Fig. 18.—Section and Plan of Blast Furnace (Obsolete Type). Deferring for the moment any description of the latest blast furnaces, we invite his attention to Fig. 17, which represents the furnace used in the first half of our century, but which now is of an obsolete type, Fig. 18 being the section and plan of the same. The lower part of Fig. 17 shows 43where the molten metal has been allowed to run out of the furnace into channels made in dry sand; first a main stream, then branches to right and left, each of these with smaller offsets on each side of it. These smaller channels are the moulds for the pigs, so called because of the fancied resemblance of their position with regard to the branch that supplied them, to the litter of a sow. They are easily broken off from the larger mass, and then form pieces about 3 ft. long with a ᗜ-shaped section, 4 in. wide, the weight being from 60 to 80 lbs. This is iron of the crudest kind, and though it is often referred to as “cast iron,” it is, as a matter of fact, not used in this state for any castings, except those of the very roughest and largest kind: a certain amount of purification is requisite in most cases. This is given by fusing the metal—along with some form of oxide and often other matters—in a cupola furnace, which is like a small blast furnace, being from 8 ft. to 20 ft. high and uses coke for fuel with a cold blast. So far from being simply iron, pig contains a large and variable proportion of other matters amounting often to 10 or 12 per cent.; and these confer upon it its fusibility. The principal one is carbon, which is found in the metal partly in the state of chemical combination with it, and partly in the form of small crystals similar to those of graphite or plumbago, disseminated through the mass. When there is a comparatively small proportion of the carbon combined with the iron, the substance is grey, and it can be filed or drilled or turned in a lathe. In white cast iron the combined carbon predominates, or is sometimes accompanied by scarcely any graphitic carbon; it is brittle and so very hard that a file makes no impression. It fuses at a lower temperature than the other varieties. A third kind is the mottled cast iron, which shows a large coarse grain when broken, and distinct points of separate graphite particles; it is tougher than the others, and therefore when cannon were made of cast iron this variety was preferred. The following table giving the percentage composition of four samples of crude cast iron will show their diversities. White. White. Mottled. Grey. Iron 88·81 89·304 93·29 90·376 Combined carbon 4·94 2·457 2·78 1·021 Graphite, or uncombined carbon ... 0·871 1·99 2·641 Silicon 0·75 1·124 0·71 3·061 Sulphur trace 2·516 trace 1·139 Phosphorus 0·12 0·913 1·23 0·928 Manganese 5·38 2·815 trace 0·834 The reader will observe that the last item in the table above is a substance that he has not yet made the acquaintance of, namely, manganese. This is a metal which in many of its chemical relations much resembles iron, and ferruginous ores usually contain a greater or less proportion of it. Manganese is of great importance in the manufacture of steel, as we shall presently see; but as a separate metal it has no application, and is obtainable in the metallic state with much difficulty. One of its oxides has however very extensive applications in the chemical arts, and others 44form acid radicles, which in combination with potash or soda give rise to useful products. The well-known “Condy’s fluid” is a solution of one of these. We have seen how malleable iron or steely iron may be directly obtained from the ores, but it has been found that on the large scale it is necessary and more economical to operate on the pig iron produced by the blast furnaces in such a manner as to remove the greater part of the foreign substances. Fig. 19.—Section of a Reverberatory Furnace. The first step in the conversion of the pig iron usually taken has been, and to a certain extent even is still, to remelt the metal in what is termed a finery furnace, a kind of forge in which a charcoal fire is urged by a cold blast, and so regulated that an excess of oxygen is supplied, or rather more than would suffice to convert all the carbon of the fuel into carbonic acid; although this is perhaps not absolutely necessary, as carbonic acid would itself supply oxygen by suffering reduction to carbonic oxide. At any rate the melted metal is exposed to an oxidizing atmosphere and constantly stirred. Many different arrangements of the furnace and details of the process have been used. For instance, where the finest quality of malleable iron was not aimed at, coke has been the fuel employed, and many shapes of furnaces, etc., have been contrived, and various additions of ores, oxides, etc., made to the charge, according to local practice and the nature of the crude iron. One marked effect of the operation is the final removal of nearly all the silicon, which is burnt or oxidized into silica, and this at once unites with oxide of iron, which is also formed, to produce a readily fusible slag of silicate of iron, and in the production of this silicate any sand attached to the pig will also take part. Much of the carbon, amounting sometimes to more than half, is also eliminated as carbonic oxide, and of what is left but little remains in the graphitic state. The action on the phosphorus is usually less marked, but there is always a notable reduction of the quantity. The sulphur is also lessened in some degree, although when coke is