Discoveries and Inventions of the Nineteenth Century

a ton or two of metal at a time. These experiments extended over a period of two and a half years, and upon them Bessemer and his partner spent about £16,000, besides the £4,000 the preliminary researches had cost. But all difficulties were at length overcome, and the process was now found capable of turning out pure iron and steel when the pure pig iron of Sweden was used in the converter. In the meantime the licensees had made no attempts practically to carry out the process, which began to be denounced as visionary: it was “a mare’s nest”; it was “a meteor that had passed through the metallurgical world, but had gone out with all its sparks.” When Bessemer again brought the subject before the public, he found that no one believed in it; everyone said, “Oh, this is the thing that made such a blaze two or three years ago, and which was a failure.” Neither iron-makers nor steel-makers would now take it up. Bessemer and his partner thereupon joined with three other gentlemen to establish at Sheffield a steel-works of their own, where the invention should be carried into full practice. In due time works were erected, and they commenced to sell steel, receiving at first very paltry orders, for such quantities as 28 lbs. or 56 lbs.; but the orders soon became larger, and afterwards very much larger, for they were underselling the Sheffield manufacturers by £20 a ton, and their steel was undistinguishable from 63the higher priced article. Bessemer had now bought his licences back again, and in the course of his second set of experiments had patented each improvement as it occurred to him, finally bringing the mechanical apparatus to the degree of efficiency requisite for practical working, without which his primary idea would have been valueless. Before directing the reader’s attention to the form the apparatus had assumed, we may transcribe what Mr. Jeans, in the work above referred to, has told about the commercial success of the Bessemer steel-making firm:— “On the expiration of the fourteen years’ term of partnership of this firm the works, which had been greatly increased from time to time out of revenues, were sold by private contract for exactly twenty-four times the amount of the whole subscribed capital, notwithstanding that the firm had divided in profits during the partnership a sum equal to fifty-seven times the gross capital, so that by the mere commercial working of the process, apart from the patent, each of the five partners retired after fourteen years from the Sheffield works with eighty-one times the amount of his subscribed capital, or an average of nearly cent. per cent., every two months,—a result probably unprecedented in the annals of commerce.” Fig. 24.—Bessemer Converter.A, Front view, showing the mouth, c; B, Section. The form of the Bessemer apparatus as it finally left the inventor’s hands may now be considered: but in certain details and arrangements some modifications, dictated by the experience and requirements of individual establishments, have been made, leaving the principles of the apparatus unchanged. Thus instead of making the converting vessel turn on trunnions, it is sometimes constructed fixed, the fluid metal after conversion being let out at a tap-hole; the number and size of the tuyères are varied; and so with the disposition of the air chamber or tuyère box, the pressure of the blast, the capacity of the converter itself, etc. In capacity converters vary between 2½ tons and 10 tons; one of medium size is shown in elevation and section in Fig. 24, and may 64be described as an egg-shaped vessel about 15 ft. high and 6 ft. diameter inside. It is strongly made of wrought iron in two parts bolted together, and is lined inside with some thick infusible coating, of which more is to be said presently. The converter swings on trunnions, one of which is hollow, and admits the blast by the pipe b to the base of the vessel, whence it passes through the passages shown at e. The thickness of the lining at e may perhaps be 20 in., and passages for the air are perforated in fire-clay tuyères, of which there may be seven, each with seven perforations of half an inch diameter. To the other trunnion is attached a toothed wheel which engages the teeth of a rack receiving motion from hydraulic pressure. The iron for the operation is melted in a furnace having its hearth above the level of the converter; and to receive its charge the latter is turned so that the molten cast iron may be poured in from a trough until its surface is nearly on a level with the lowest of the tuyères. The blast having been turned on, the hydraulic power is set to work and the converter is slowly brought to an upright position. The pressure of the current of air prevents any of the fluid metal from entering the blow-holes. The blast of cold air is continued until all the silicon and carbon have been removed by oxidation. If the production is to be steel, there is then added to the contents of the converter, placed in position to receive it, a certain weight of melted cast iron of a special constitution, and the blow is resumed for a few minutes; or in more recent practice this special metal is added to the fluid metal run out of the converter into a spacious ladle in known quantity. On this addition an intense action takes place, attended by an extremely brilliant flame and a throwing out of cinder or slag. The metal thus added to the decarbonized iron is a carbonized alloy of iron and manganese obtained from an ore naturally containing the latter metal, and scarcely any phosphorus or sulphur. The charcoal pig from this ore is called spiegeleisen (German = mirror-iron) from its brilliant reflecting facets; it contains from 12 to 20 per cent. of manganese, with about 5 per cent. of carbon, and a considerable proportion of silicon. An exact chemical analysis of the particular spiegeleisen having been previously made, it is known what proportion of it is to be added to the decarbonized iron in order to convert this into a steel with any required content of carbon. The manganese probably acts by combining with oxide of iron diffused through the mass, and together with the silicon forming the very easily separated slag which is ejected. The whole series of operations connected with the Bessemer process may be easily followed by the help of Fig. 25, which is taken from a beautiful model in the Museum of Practical Geology. This model, which was presented to the museum by Mr. Bessemer himself, represents every part of the machinery and appliances of the true relative sizes. C is the trough, lined with infusible clay, by which the liquid pig iron is conveyed to the converters, A. The hydraulic apparatus by which the vessels are turned over is here below the pavement, but the rack which turns the pinion on the axis of the converter is shown at B. The vessel into which the molten steel is poured from the converter is marked E, and this vessel is swung round on a crane, D, so as to bring it exactly over the moulds, placed in a circle ready to receive the liquid steel, which on cooling is turned out in the form of solid ingots. The valves which control the blast, and those which regulate the movements of the converter through the hydraulic apparatus, are worked by the handle seen at H. The 66crane, or revolving table, D, is also under perfect control, so that the crude pig iron is converted into steel, and the moulds are filled with a rapidity and ease that are positively marvellous to a spectator. Fig. 25.—Model of Bessemer Steel Apparatus. The development of the Bessemer process soon had the effect of so reducing the price of steel that this material came into use for almost every purpose for which iron had previously been employed, such as railway bars, girders, etc., for bridges, boiler plates, etc., for all which “steely iron” containing only 0·12 to 0·40 per cent. carbon proved admirably adapted. The practical success of the Bessemer process had not long been demonstrated commercially by the inventor and his partners at Sheffield before other firms began the manufacture: so that in 1878 there were in Great Britain alone twenty-seven establishments making Bessemer steel and using 111 converters. It may give an idea of the magnitude the Bessemer steel manufacture had attained even at that time if we quote the cost of erecting a complete plant for two 5–ton converters: it was £44,400, as given in a detailed estimate. In all these cases pig iron from ores free from phosphorus and sulphur had to be used, for as we have seen the converter failed to eliminate these vitiating elements. Imported pig ores had in general to be used, or pig from the limited supply of British hæmatite ores in West Cumberland. The Barrow Hæmatite Steel Company engaged in the production of Bessemer steel on a very large scale, having by 1878 erected no fewer than sixteen converters of the capacity of 6 tons each. In the meanwhile many efforts were made to discover some method of eliminating phosphorus, so that the ordinary qualities of British pig iron, and iron derived in any part of the world from the coarse phosphorized ores, might be available for the converter. Many of the methods then devised proved correct in principle and feasible in practice; but as, for sundry reasons, none of them came extensively into use, we need not here allude to them further. The solution of the problem was announced in 1879. Some years before, G. J. Snelus had come to the conclusion that with a siliceous lining it would be impossible to eliminate phosphorus in the Bessemer converter, and that some refractory substance of a basic character must be sought for in order that the slag produced should be in a condition to absorb the phosphoric acid as fast as it is produced. He patented in 1872 the use of magnesian limestone as a material for the lining; as that substance when intensely heated became very hard and stony, being in that condition quite unaffected by water. Two young chemists, Messrs. Thomas and Gilchrist, apparently without being aware of Mr. Snelus’s conclusions, had also convinced themselves that the chief deficiency in the Bessemer process was due to the excess of silica in the slag, and in 1874 they began to try the effect of basic linings, and also of basic additions, such as lime, etc., to the charge in the converter, so that the lining itself should not be worn out by entering into the slag. Their results proved that phosphorus could be eliminated when the slag contained excess of a strong base. An example of an operation at Bolckow, Vaughan, & Company’s Eston works with the highly phosphorized Cleveland pig iron may be quoted. The basic-lined converter received first 9 cwt. of lime, then 6 tons of metal. When the blast at 25 lbs. pressure was turned on, the silicon began at once to burn; for three minutes the carbon was not affected, but for fourteen minutes longer it regularly diminished, the silicon keeping pace with it. After 67the blow had been continued for thirteen minutes from the commencement, the converter was turned down to allow of the further introduction of 19½ cwt. of a mixture of two parts of lime with one of oxide of iron. So long as 1·5 per cent. of carbon remained in the metal the phosphorus was untouched, and at the end of the blow, i.e. when the flame dropped, only one-third of it had been eliminated; it still formed 1 per cent. of the metal. The blast continued for another two minutes brought it down to ¼ per cent., and in one more minute only a trace was left. Most of the sulphur was got rid of at the same time. From Cleveland pig, thus de-phosphorized in the Bessemer converter, large quantities of steel rails were rolled for the