Discoveries and Inventions of the Nineteenth Century

in innumerable fiery bubbles through, the whole fluid mass, the metal absorbs the greater part of it, and its temperature becomes immensely increased, and by the expiration of the fifteen minutes before named that part of the carbon which appears mechanically mixed and diffused throughout the crude iron has been entirely consumed: the temperature however is so high that the chemically combined carbon now begins to separate from the metal, as is at once indicated by an immense increase in the volume of flame rushing out of the throat of the vessel. The metal in the vessel now rises several inches above its natural level, and a light frothy slag makes its appearance and is thrown out in large foam-like masses. This violent eruption of cinder generally lasts about five or six minutes, when all further appearance of it ceases, a steady and powerful flame replacing the shower of sparks and cinder which always accompanies the boil. The rapid union of carbon and oxygen which thus takes place adds still further to the temperature of the metal, while the diminished quantity of carbon present allows a part of the oxygen to combine with the iron, which undergoes combustion and is converted into an oxide. At the excessive temperature that the metal has now acquired, the oxide as soon as formed undergoes fusion, and forms a powerful solvent of those earthy bases that are associated with the iron; the violent ebullition which is going on mixes most intimately the scoria and metal, every part of which is thus brought in contact with the fluid oxide, which will thus wash and cleanse the metal most thoroughly from the silicon and other earthy bases which are combined with the crude iron, while the sulphur and other volatile matters which cling so tenaciously to iron at ordinary 60temperatures are driven off, the sulphur combining with the oxygen and forming sulphurous acid gas. “The loss in weight of crude iron during its conversion into an ingot of malleable iron was found, on a mean of four experiments, to be 12½ per cent., to which will have to be added the loss of metal in the finishing rolls. This will make the entire loss probably not less than 18 per cent. instead of about 28 per cent., which is the loss on the present system. A large portion of this metal is however recoverable by heating with carbonaceous gases the rich oxides thrown out of the furnace during the boil. These slags are found to contain innumerable small grains of metallic iron, which are mechanically held in suspension in the slags and may be easily recovered. “I have before mentioned that after the boil has taken place a steady and powerful flame succeeds, which continues without any change for about ten or twelve minutes, when it rapidly falls off. As soon as this diminution of flame is apparent the workman will know that the process is completed, and that the crude iron has been converted into pure malleable iron, which he will form into ingots of any suitable size and shape by simply opening the tap-hole of the converting vessel and allowing the fluid malleable iron to flow into the iron ingot moulds placed there to receive it. The masses of iron thus formed will be free from any admixture of cinder, oxide, or other extraneous matters, and will be far more pure and in a forwarder state of manufacture than a pile formed of ordinary puddle bars. And thus it will be seen that by a single process, requiring no manipulation or particular skill, and with only one workman, from three to five tons of crude iron pass into the condition of several piles of malleable iron in from thirty to thirty-five minutes, with the expenditure of about a third part the blast now used in a finery furnace, with an equal charge of iron, and with the consumption of no other fuel than is contained in the crude iron. “To those who are best acquainted with the nature of fluid iron, it may be a matter of surprise that a blast of cold air forced into melted crude iron is capable of raising its temperature to such a degree as to retain it in a perfect state of fluidity after it has lost all its carbon and is in the condition of malleable iron, which, in the highest heat of our forges, only becomes softened into a pasty mass. But such is the excessive temperature that I am enabled to arrive at with a properly shaped converting vessel and a judicious distribution of the blast, that I am enabled not only to retain the fluidity of the metal, but to create so much surplus heat as to remelt all the crop-ends, ingot-runners, and other scrap that is made throughout the process, and thus bring them, without labour or fuel, into ingots of a quality equal to the rest of the charge of new metal.... “To persons conversant with the manufacture of iron, it will be at once apparent that the ingots of the malleable metal which I have described will have no hard or steely parts, such as are found in puddled iron, requiring a great amount of rolling to blend them with the general mass, nor will such ingots require an excess of rolling to expel cinder from the interior of the mass, since none can exist in the ingot, which is pure and perfectly homogeneous throughout, and hence requires only as much rolling as is necessary for the development of fibre; it therefore follows that, instead of forming a merchant bar, or rail, by the union of a number of separate pieces welded together, it will be far more simple and less 61expensive to make several bars or rails from a single ingot. Doubtless this would have been done long ago had not the whole process been limited by the size of the ball which the puddler could make. “The facility which the new process affords of making large masses will enable the manufacturer to produce bars that, in the old mode of working, it was impossible to obtain; while at the same time it admits of the use of more powerful machinery, whereby a great deal of labour will be saved and the process be greatly expedited.... I wish to call the attention of the meeting to some of the peculiarities which distinguish cast steel from all other forms of iron, viz., the perfectly homogeneous character of the metal, the entire absence of sand-cracks or flaws, and its greater cohesive force and elasticity, as compared with the blister steel from which it is made,—qualities which it derives solely from its fusion and formation into ingots, all of which properties malleable iron acquires in like manner by its fusion and formation into ingots in the new process; nor must it be forgotten that no amount of rolling will give the blister steel, although formed of rolled bars, the same homogeneous character that cast steel acquires by a mere extension of the ingot to some ten or twelve times its original length.... “I beg to call your attention to an important fact connected with the new process which affords peculiar facilities for the manufacture of cast steel. At that stage of the process immediately following the boil the whole of the crude iron has passed into the condition of cast steel of ordinary quality. By the continuation of the process the steel so produced gradually loses its small remaining portion of carbon, and passes successively from hard to soft steel, and from soft steel to steely iron, and eventually to very soft iron; hence, at a certain period of the process, any quality of metal may be obtained. There is one in particular which by way of distinction I call semi-steel, being in hardness about midway between ordinary cast steel and soft malleable iron. This metal possesses the advantage of much greater tensile strength than soft iron; it is also more elastic, and does not readily take a permanent set, while it is much harder and is not worn or indented so easily as soft iron; at the same time it is not so brittle or hard to work as ordinary cast steel. These qualities render it eminently well adapted to purposes where lightness and strength are specially required, or where there is much wear, as in the case of railway bars, which from their softness and lamellar texture soon become destroyed. The cost of semi-steel will be a fraction less than iron, because the loss of metal that takes place by oxidation in the converting vessel is about 2½ per cent. less than it is with iron; but as it is a little more difficult to roll, its cost per ton may fairly be considered to be the same as iron; but as its tensile strength is some 30 or 40 per cent. greater than bar iron, it follows that for most purposes a much less weight of metal may be used than that so taken. The semi-steel will form a much cheaper metal than any we are at present acquainted with. These facts have not been elicited from mere laboratory experiments, but have been the result of working on a scale nearly twice as great as is pursued in our largest iron works, the experimental apparatus doing 7 cwt. in thirty minutes, while the ordinary puddling furnace makes only 4½ cwt. in two hours, which is made into six separate balls, while the ingots or blooms are smooth, even prisms, 10 in. square by 30 in. in length, weighing about equal to ten ordinary puddle balls.” The startling novelty of the methods and results described in this 62paper had the effect of paralyzing discussion at the time. But soon the voice of detraction was heard; many iron-masters ridiculed the idea of producing iron and steel without fuel, and indeed it may have been observed, the title of the paper notwithstanding, that first the silicon and carbon, and then the iron itself, really supplied the fuel. And we must remember that malleable iron in a molten state was then deemed an impossibility, for the hottest furnaces then known could not effect the fusion, however prolonged their action might be, yet Bessemer was to obtain five tons in this condition in the short space of half an hour with no other aid than cold air. Then it was said that Bessemer’s process of forcing air into melted cast iron had no claim of novelty, for it had been tried before and found valueless. Some iron-masters on trying experiments on a small scale and with imperfect appliances met with failures, and discredited the process at once; but five large establishments paid for licences sums amounting to £26,500 within three weeks of the reading of the paper. At the works of the Dowlais Iron Co., in South Wales, who were the first licensees, the first converter was set up under Bessemer’s personal superintendence, and at the first operation five tons of iron were produced direct from the blast furnace pig. This apparently satisfactory result proved quite otherwise when this iron came to be practically tested; for it was found quite useless! It was both “cold-short” and “red-short,” to use the technical terms,—the former of which means that although the sample may be welded, it is when cold brittle and rotten; the latter means that at a low red heat it breaks and crumbles under the hammer. Further trials were made, new experiments instituted, but the success that attended Bessemer’s early experiments could not be repeated, and as yet no one knew the reason why. Now it so happened that in the preliminary experiments an exceptionally pure pig iron had been made use of containing little or no phosphorus or sulphur, substances very deleterious in iron, and still more so in steel. With the capital obtained by the sale of his licences Bessemer quietly set to work to investigate the cause of his non-success, making daily experiments with