Discoveries and Inventions of the Nineteenth Century

preliminary notes of the character of the chemical actions, and of some properties of the substances that will have to be referred to. It is certainly the case that people in general, and even people very well informed in other subjects, have but the vaguest notions of the nature of chemical actions, and of the meaning of the terms belonging to that science. For example, one of our most popular and justly esteemed writers, treating of the very subject of iron extraction, calls the ore a matrix, thereby implying that the iron as metal is disseminated in detached fragments throughout the mass, which is a conception inconsistent with the facts. The reader will be in a more advantageous position for understanding the relation of the ores of iron to the metal, if he will follow in imagination, or still better in reality, a few observations and experiments like the following—of which, however, he is recommended not to attempt the chemical part unless he is himself practically familiar with the performance of chemical operations, or can obtain the personal assistance of someone who is. Taking, say, a few common iron nails, let him note some obvious properties they possess: they have weight—are hard and tough so that they cannot be crushed in a mortar—are opaque to light—if a smooth surface be produced on any part, it will show that peculiar shiny appearance which is called metallic lustre, in this case without any decided colour—they are not dissolved by water as sugar or salt is—and are attracted by a magnet. If several of the nails be heated to bright redness they may be hammered on an anvil into one mass, and this may be flattened out into a thin plate, or it may be shaped into a slender rod and then drawn out into wire; or otherwise the nails may be converted into the small fragments called iron filings. In these several forms the nails, as nails, will have ceased to exist; but the material of which they were formed will remain 34unchanged, and each and every part of it however large or small will continue to exhibit all the properties noted above as belonging to the substance of the nails, which in the cases supposed has undergone merely physical change of shape. Treating our nails in yet another way, we may proceed to subject them to a chemical change, by an experiment very simple in itself, but involving certain precautions, by neglect of which the tyro in chemical operations would incur some personal risks; these might however be obviated by using only very small quantities of the materials (a mere pinch of iron filings and a few drops of sulphuric acid), when the results would still be sufficiently observable. A few of the iron nails having been placed in a flask of thin glass, we pour upon them a mixture of oil of vitriol (sulphuric acid) and water, which has previously been prepared by gradually adding 1 measure of the acid to 5 measures of water. The action that takes place is greatly accelerated by heat, and indeed the contents should be heated to boiling by standing the flask on a layer of fine sand spread on an iron plate and gently heated from below. The nails will soon disappear, being completely dissolved by the acid liquid, and the turbid solution should be filtered through filtering paper as rapidly as possible and while still hot. This turbid and dirty looking condition is due to foreign matters in the nails, for these never consist of pure iron. The filtered liquid is set aside to cool in a closed vessel, in which after a time will be found a deposit of crystals of a pale bluish-green colour. The liquor above these having been poured off, the crystals are to be rinsed with a very small quantity of cold water, and then dried between folds of blotting-paper, after which they are ready for examination. The quantity of the diluted acid put into the flask should have a certain proportion to the weight of the nails; about 5 fluid ounces to 1 ounce of iron will be found convenient, for if less is used the nails will not be entirely dissolved, and an excess will tend to keep the crystals in solution instead of depositing them when cold. The nails—as such—will now have passed out of existence: can we say that the iron that formed them exists in the crystals? Certainly not as the metal iron, for every property of the metal will have disappeared. The crystals are brittle, can be crushed in a mortar—they are translucent—they show no metallic lustre, but only glassy surfaces—they are readily dissolved by water—they are not attracted by a magnet. The most powerful lens will fail to show the least particle of iron in them; they have in their properties no assignable relation to the metal of the nails, but are matter of quite another sort; and be it noted that this entire otherness is the special and characteristic sign of chemical change. So complete is the transformation in the case we have been considering that it would never have been said that iron was contained in these crystals, but rather that the metal had for ever passed out of existence, but for one circumstance; and that is, that by subjecting the crystals to certain processes of chemical analysis we can again obtain from them the iron in metallic state. Nay more, we should find the weight of metal so obtained to be exactly equal to that of the pure iron dissolved from the original nails, supposing of course that we operated upon the whole of the crystalline matter so produced. The inference therefore is that although every property of the iron appeared to be absent from the crystals, the iron entering in them retained there its original weight, and the correct statement of the change would be, that in the crystals the iron had lost all its original properties SAVE ONE, namely, its weight, or gravitating force, if we choose to call it 35so, a property belonging to it in common with every material substance. Chemical analysis can also separate from the crystals their other constituents and weigh them apart—so much water and so much sulphuric acid—and when to these weights that of the iron is added, the sum exactly makes up the weight of the crystals. A still simpler experiment, which may be performed by anyone with the greatest ease, may serve as a further illustration of the profound nature of the change in the properties of bodies brought about by chemical combination, and it will also serve as the occasion of directing attention to a remarkable circumstance that invariably characterizes such changes, and one that should always be present in our minds when we are considering them. A yard of flat magnesium wire can be bought for a few pence, and after its metallic character has been observed in the silvery lustre disclosed by scraping the dull white surface, a few inches is to be held vertically by a pair of tongs, or by inserting one extremity in a cleft at the end of a stick, then the lower part is brought into contact with a candle or gas flame. The metal will instantly burn with a dazzlingly brilliant light, and some white smoke (really fine white solid particles) will float into the air; but if a plate be held under the burning metal, some of the smoke will settle upon it, together with white fragments that have preserved some shape of the metallic ribbon, but which a touch will reduce into a fine white powder, identical with the well-known domestic medicine called “calcined magnesia”—a substance totally different from the metal magnesium. The reader will scarcely require to be told that in this burning the metal is entering into combination with the oxygen of the air—by which that invisible gas somehow becomes fixed in these solid white particles, so entirely unlike itself. But this experiment might be so arranged that the quantities of magnesium and oxygen entering into the magnesia could be weighed. For this purpose special appliances would be required in order to ensure complete combustion of the metal, for in the experiment as just described some small particles are liable to be shielded from the oxygen by a covering of magnesia, and the arrangement would have to be such that the whole of the white powder could be gathered up and weighed. In the absence of such appliances, and of a delicate balance, together with the skill requisite for their use, the reader must for the time be contented to take our word for what would be the result. In every experiment the magnesia would be found heavier than the metal burned in the proportion of 5 to 3; in other words, magnesia always contains (so the phrase runs) 3 parts of magnesium combined with 2 of oxygen: never more nor less. A definite proportion between the weights of the constituent substances characterizes every chemical combination, and when this is once determined in a single sample of the compound, it is determined for every portion of the same, wherever found or however produced. But each compound has its own particular proportion, that is, the quantitative relations are different for each. For example, the two constituents of water, hydrogen and oxygen, are combined in the ratio of 1 to 8, etc.; and oxygen combines with metals in a ratio different in each case. Then occasionally the same ratio of constituents occurs in compounds of different composition. The elementary student is apt to suppose that this is because of the law which he finds stated, probably in almost the first page of his text-book: “Every compound contains its elements in definite and invariable proportions”; and even well-educated people entertain 36the idea of the fact being “governed by” or “obeying” the law just quoted,—a misconception arising from the other use of the word “law,” as signifying an enactment. The real case however is the converse; namely, that a multitude of facts like that above stated have governed the law, and caused it to be what it is—the general statement of many observed facts. We have assumed that the reader’s chemical knowledge had already made him aware that in every case of ordinary combustion the oxygen of the atmosphere is in the act of entering into combination with the burning body: as with the magnesium, so with a coal fire, a gas flame, or a burning candle; only in these last cases the products of the combustion pass away invisibly. The candle by burning disappears from sight, but its matter is not lost, and as in the case of magnesium, the compounds it forms weigh more than the unburnt candle. The experiment is commonly shown in courses of elementary lectures on chemistry, of so burning a candle that the invisible products are retained in the apparatus, instead of being dissipated in the atmosphere, and the increase of weight of the burnt candle over the original one is demonstrated by the balance. Important as is the part played by oxygen in all chemical actions on the earth, the composition of the atmosphere was not understood until the end of the eighteenth century, and it was well on into the nineteenth before the quantities of its constituents were accurately determined. Now everyone knows that air is mainly made up of a mixture of the two gases oxygen and nitrogen. A mixture of two or more things is very different from a chemical combination of them; for in the former each ingredient retains its own properties. (See Air in Index.) Nitrogen being an inert gas that takes no part in combustion, or in the ordinary chemical actions of the air, acts therein simply as a diluent of the oxygen. It is necessary in relation to our present subject to bear this in mind, as well as