Discoveries and Inventions of the Nineteenth Century

all their transactions, to send a copy of it every month to the head of the police, and to produce it when required. It is needless to say that extraordinary precautions are taken to prevent the native workmen from secreting diamonds. And any person even finding a diamond, and neglecting to report the circumstance to the proper quarter at once, is liable to the pains and penalties above mentioned. The “blue ground” was at first supposed to be the original home of the diamond, within which it had somehow taken its shape. But no satisfactory explanation was forthcoming as to the state of the carbon before its solidification into the crystalline form. The more general opinion has been in favour of a volcanic origin due to very high temperature; and although the “blue ground” itself is clearly not the ordinary erupted matter of volcanoes due to igneous fusion, the geology points to the district having been the scene of very active and extensive volcanic energies at more than one remote period, for the bed of the Karoo inland sea has been several times covered by level sheets of molten matter extruded somewhere from below; but not through the “pipes,” which were blown out ages afterwards. The strata of basalt and of hornblendic mineral, which extend horizontally over great areas in the Karoo formation, are of igneous origin, as are also some nearly vertical dykes of trap rock, about 7 feet wide, that are found traversing the “blue ground” in certain directions. These intrusive dykes are of course more recent than the formation of the blue ground, and that is itself later than the production of the pipes. The fact of many fragments of crystals being found in the “blue ground” does not comport with the theory that supposes it to be the matrix; and besides this, many of the diamonds show scratches, and as these are producible only by other diamonds, it would appear that they must all have travelled in company, some part of their journey at least. Carbon in any form is quite infusible at the highest temperature we have hitherto been able to produce, although an incipient softening under the influence of the electric arc has been suspected. Professor Dewar, an English chemist, basing his data on analogies with other substances, and on purely theoretical grounds, has calculated that the melting temperature of carbon is near 3,600° C. (6,512° F.), and that it cannot remain in a liquid state at a temperature exceeding 5,527° C., when its vapour would have a tension equivalent to a pressure of 15 tons on the square inch. So far as these deductions are correct, both the melting point of carbon and the boiling point of its liquid must lie within the range of temperature expressed by 3,600° C. and 5,527° C. The most intense heat we can produce is that developed in the electric arc discharge, and an eminent French chemist and metallurgist, M. Moissan, by employing special arrangements and very powerful currents, has thus been able to obtain in his “electric furnace” a temperature estimated at 3,500° C., which nearly approaches the lower of the above-mentioned limits, and he has thereby produced many new and unexpected chemical combinations of refractory elements. Among the most striking of his 712results is the formation artificially of real crystalline diamonds. He found that carbon is freely dissolved by several of the metals in fusion at the temperature of the electric furnace. When the carbon separated from the metals, as they cooled and became solid, it was always in the condition of graphite. The carbons of the electric poles were readily attacked by molten iron, and it was from the solution of carbon in iron that Moissan prepared his diamonds. The fact of carbon thus combining with iron was of course no discovery, as the reader already knows; and the resulting combination was found, on allowing the metal to cool, to be simply cast iron, the greater part of the carbon separating out in the graphitic form. But M. Moissan, having studied the conditions of the Kimberley mines, and recognizing the probability of the diamonds having taken their origin at very great depths, where the pressure due to the weight of superincumbent strata would be immense, was struck with the idea of pressure being in some way a factor in their formation; and it occurred to him that the carbon might separate from its liquid condition in the iron in the crystalline, and not in the graphitic form, if the solidification could be effected under great pressure. The apparently insurmountable difficulty of applying an enormous pressure to a small quantity of molten iron (half a pound) yielded to the experimenter’s ingenuity. He took advantage of the circumstance that cast iron at the moment of solidification expands, a property upon which depends its use for many purposes. If then the fused mass were suddenly cooled on the outside, we should have a shell of solid iron enclosing a nucleus of still fluid metal, which, on cooling in its turn, would tend to expand, and by so doing would exert a great pressure within the shell by which it was confined. At first Moissan plunged his glowing crucible into cold water, but a method of more rapidly cooling it was to immerse it in melted lead. It seems a strange proceeding to cool the crucible by surrounding it with hot metal, yet the difference of the temperatures was sufficient to produce the desired effect, the cooling contact of water not really operating on the intensely heated body, which becomes separated from the liquid by a coating of steam. When the mass of iron was dissolved off, diamonds of all kinds were found in the residue, and, though extremely small, some crystals were perfect in shape and colour; every variety that occurred in the mines being found reproduced in tiny size. There was also some graphite in the residue. Many more crystals of “pure water” were obtained by the lead-cooling than by the water-cooling, as the former process gave some flawless cubes and octahedra. The largest of the set was only 150 inch across, and although of perfect form when first extracted, within the course of three months it had spontaneously split up into fragments. There was evidently no danger of M. Moissan’s manufacture of diamonds from coke causing consternation at Kimberley; though it would not be without interest to speculate upon the consequences had the French savant achieved the greater triumph of turning out carbon crystals in every respect equal to the productions of nature’s own laboratories. What a drop there would have been in the shares of the De Beers Mines Consolidated! What heaviness of heart would have fallen upon those great ladies who exult in the exclusive possession of priceless tiaras and precious necklaces flashing with the resplendent gems! From a scientific point of view, M. Moissan’s fabrication of even those minute crystals, which so soon spontaneously crumbled into fragments, 713is a distinct and valuable success; for, notwithstanding their diminutive size and instability, they show us that art has so far succeeded in imitating the processes of nature, that some of her secrets have been revealed. Though we know the exact chemical composition of all kinds of crystallized minerals, very very few of these have we been able to imitate artificially. Nor is this to be wondered at; for nature’s resources are immense compared with ours: she can command temperatures unlimited by which to form her solutions or liquefactions; prodigious pressures to keep them close; and time immeasurable—geological time—in which to let them cool, and their particles freely coalesce into geometric forms. Human agency, being obviously unable to reproduce, even on the smallest scale, such conditions as attended the deposition and slow cooling of the earth’s crust, may not hope to rival the products of the planet’s prime. So the fair owners of the earth-born gems may possess their souls in peace, free from any fear of the chemists’ crucibles; and the Kimberley Diamond Companies are not likely to suffer panics from the results of scientific researches, and probably will continue to pay their handsome dividends for time indefinite. But curiously enough, a discovery of the latest years of our century has revealed the existence of diamonds in a region not mapped by the most advanced of geographers—a region which indeed cannot be defined by degrees of latitude and longitude. In the recesses of an unquestionable meteorite—one of those celestial lumps of iron of which mention has been made in the earlier pages of this volume—real diamonds have been found. These quite resembled the products of M. Moissan’s experiments, being extremely small, but including clear and perfectly shaped crystals, associated with black ones, and also with much graphite in more or less definite forms. So very limited, however, could be the quantity of diamonds obtainable from this hitherto unsuspected source, that even if they rivalled in quality the finest stones from the South African mines, it might be difficult to form a “Company” for their exploitation. Still, there is the possibility of some one falling in with a little meteorite containing some mature full-sized carbon crystals, and such a one might be considered equally fortunate with the finder of the famous Australian nugget “Welcome” (£25,000). The association of diamonds with the ferruginous matter of the “blue ground” in the Kimberley pipes, their crystallization out of iron in M. Moissan’s experiments, and their presence in iron meteorites, would seem to point to special relations between the two elements, iron and carbon. Some of these relations are exemplified in another way by the profound modification effected in the physical properties of iron, by its combination with a very small quantity of carbon, as in some kinds of steel; or again, by the differences between white cast iron and grey cast iron, as determined by the condition of the carbon in each. 714 Fig. 335.—Portrait of Sir Humphrey Davy.